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https://hdl.handle.net/10216/97011
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DC Field | Value | Language |
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dc.creator | da Silva, MAVR | |
dc.creator | Ana I M C L Lobo Ferreira | |
dc.creator | Maciel, FM | |
dc.date.accessioned | 2022-09-08T16:24:18Z | - |
dc.date.available | 2022-09-08T16:24:18Z | - |
dc.date.issued | 2010 | |
dc.identifier.issn | 0021-9614 | |
dc.identifier.other | sigarra:48812 | |
dc.identifier.uri | https://hdl.handle.net/10216/97011 | - |
dc.description.abstract | The present work is part of a research program on the energetics of the linear 4-n-alkoxybenzoic acids, aiming the study of the enthalpic effect of the introduction of an alkoxy chain in the position 4- of the benzoic acid ring. In this work, we present the results of the thermochemical research on 4-n-alkoxybenzoic acids with the alkoxy chain length n = 2, 4, and 8. The standard (p degrees = 0.1 MPa) molar enthalpy of formation of crystalline 4-ethoxybenzoic acid, 4-butoxybenzoic acid, and 4-(octyloxy)benzoic acid was measured, at T = 298.15 K, by static-bomb calorimetry. These values, combined with the values of standard molar enthalpies of sublimation, were used to derive the standard molar enthalpies of formation in the gaseous phase. [GRAPHICS] From those experimental values, the standard molar enthalpies of formation, in the gaseous phase, at T = 298.15 K, are interpreted in terms of structural contributions to the energetics of the substituted benzoic acids and compared with the same parameters estimated from the Benson's Group Method. | |
dc.language.iso | eng | |
dc.rights | restrictedAccess | |
dc.subject | Química física, Engenharia química | |
dc.subject | Physical chemistry, Chemical engineering | |
dc.title | Experimental standard molar enthalpies of formation of some 4-alkoxybenzoic acids | |
dc.type | Artigo em Revista Científica Internacional | |
dc.contributor.uporto | Faculdade de Ciências | |
dc.identifier.doi | 10.1016/j.jct.2009.08.007 | |
dc.identifier.authenticus | P-003-9EG | |
dc.subject.fos | Ciências da engenharia e tecnologias::Engenharia química | |
dc.subject.fos | Engineering and technology::Chemical engineering | |
Appears in Collections: | FCUP - Artigo em Revista Científica Internacional |
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File | Description | Size | Format | |
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48812.pdf Restricted Access | 185.89 kB | Adobe PDF | Request a copy from the Author(s) |
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