Please use this identifier to cite or link to this item: https://hdl.handle.net/10216/103871
Author(s): M. C. Campo
A. M. Ribeiro
A. Ferreira
J. C. Santos
C. Lutz
J. M. Loureiro
A. E. Rodrigues
Title: New 13X zeolite for propylene/propane separation by vacuum swing adsorption
Issue Date: 2013
Abstract: Adsorption equilibrium isotherms for propane and propylene on a new 13X zeolite from CECA were measured at three temperatures (323, 373, 423 K) up to 5 bar. Maximum capacities of 3.47 and 3.08 mol/kg were found for propylene and propane, respectively. These values are significantly higher than those reported in literature. Adsorption isotherms were fitted with Toth equation. Heats of adsorption were calculated as a function of loading from experimental data with Van't Hoff equation leading to 53 kJ/mol and 35 kJ/mol for propylene and propane, respectively; values were also obtained from fitting with Toth equation. Single and binary breakthrough curves were measured and simulated with a mathematical model for fixed bed adsorbers. A 5-step VSA cycle was also simulated to produce 99.5% propylene from a 25:75 propane/propylene mixture; experimental validation confirms a good prediction. Propylene was obtained with a purity of 99.54%, a recovery of 85% and a productivity of 1.46 mol(C3H6)/kg(ads)/h.
Subject: Engenharia química
Chemical engineering
Scientific areas: Ciências da engenharia e tecnologias::Engenharia química
Engineering and technology::Chemical engineering
URI: https://repositorio-aberto.up.pt/handle/10216/103871
Related Information: info:eu-repo/grantAgreement/FCT - Fundação para a Ciência e Tecnologia/Projetos Estratégicos/PEst-C/EQB/LA0020/2013/PROJECTO ESTRATÉGICO - LA 20 - 2013-2014/LA 20
Document Type: Artigo em Revista Científica Internacional
Rights: restrictedAccess
Appears in Collections:FEUP - Artigo em Revista Científica Internacional

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