Please use this identifier to cite or link to this item:
https://hdl.handle.net/10216/164901| Author(s): | Maria Eugénia Macedo Elena Gómez Irene Domínguez Ángeles Domínguez |
| Title: | Ionic Liquids-Based Aqueous Biphasic Systems with Citrate Biodegradable Salts |
| Issue Date: | 2018 |
| Abstract: | New ionic liquids aqueous biphasic systems (ABS) containing the imidazolium and pyrrolodinium cation combined with dicyanamide anion and citrate organic salts are investigated. Several ionic liquids (five in total) were evaluated toward their capacity to create aqueous biphasic systems in the presence of two low environmental impact organic salts: potassium and sodium citrate. The capacity of these ILs to form two liquid phases is discussed regarding the alkyl chain length and the cation core of the IL. Besides, the effect of the citrate salt on the phase behavior has been also addressed. To study the capacity of the ABS the binodal curves were determined at T = 298.15 K and atmospheric pressure. Finally, a comparison between the experimental results obtained here and the literature values was carried out. |
| Subject: | Ciências Tecnológicas, Ciências da engenharia e tecnologias Technological sciences, Engineering and technology |
| Scientific areas: | Ciências da engenharia e tecnologias Engineering and technology |
| DOI: | 10.1021/acs.jced.7b00849 |
| URI: | https://hdl.handle.net/10216/164901 |
| Related Information: | info:eu-repo/grantAgreement/Comissão de Coordenação e Desenvolvimento Regional do Norte/P2020|Norte2020-Projetos Integrados ICDT/NORTE-01-0145-FEDER-000006/Advanced Industrial Processes and Materials for a Sustainable North Region of Portugal2020/AIProcMat@N2020 |
| Document Type: | Artigo em Revista Científica Internacional |
| Rights: | openAccess |
| Appears in Collections: | FEUP - Artigo em Revista Científica Internacional |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 272404.pdf | 762.13 kB | Adobe PDF |  View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.