Please use this identifier to cite or link to this item: https://hdl.handle.net/10216/106704
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dc.creatorX. Chen
dc.creatorS. A. C. Carabineiro
dc.creatorP. B. Tavares
dc.creatorJ. J. M. Orfão
dc.creatorM. F. R. Pereira
dc.creatorJ. L. Figueiredo
dc.date.accessioned2019-01-31T08:31:44Z-
dc.date.available2019-01-31T08:31:44Z-
dc.date.issued2014
dc.identifier.issn2213-3437
dc.identifier.othersigarra:65268
dc.identifier.urihttps://repositorio-aberto.up.pt/handle/10216/106704-
dc.description.abstractLanthanum-containing mixed oxides (La-Co and La-Cu) were synthesized by several methods: exotemplating, evaporation, glycine-nitrate and glycine-nitrate-exotemplating. Samples were characterized by thermogravimetry and differential scanning calorimetry, N2 adsorption, temperature programmed reduction, scanning electron microscopy and X-ray diffraction. The materials obtained were tested as catalysts for ethyl acetate oxidation, as a model volatile organic compound. La-Cu samples showed poor catalytic performance, but La-Co materials were much more active than the individual components. Catalytic activity seems to be mainly determined by the easiness of reduction of the catalysts, which is related to the availability of oxygen from the lattice. Catalysts containing Co or Cu in excess of La (on a molar base) were more active than the corresponding mixed oxides consisting of equal amounts of La and the transition metal. Samples prepared by the evaporation method were more active than those prepared by exotemplating, for the same molar ratio. Samples prepared by evaporation and glycine-nitrate methods calcined at 600°C had a better performance than the corresponding oxides calcined at 300°C. The most active sample found in this study was the La-Co mixed oxide prepared by the glycine nitrate method and calcined at 600°C, 100% conversion of ethyl acetate to H2O and CO2 being achieved at 230°C.
dc.language.isoeng
dc.relationinfo:eu-repo/grantAgreement/FCT - Fundação para a Ciência e Tecnologia/Programa de Financiamento Plurianual de Unidades de I&D/PEst-C/EQB/LA0020/2011/Projeto Estratégico-LA 20 - 2011-2012/LA 20
dc.relationinfo:eu-repo/grantAgreement/FCT - Fundação para a Ciência e Tecnologia/Projetos Estratégicos/PEst-C/EQB/LA0020/2013/PROJECTO ESTRATÉGICO - LA 20 - 2013-2014/LA 20
dc.rightsrestrictedAccess
dc.subjectEngenharia química, Engenharia química
dc.subjectChemical engineering, Chemical engineering
dc.titleCatalytic oxidation of ethyl acetate over La-Co and La-Cu oxides
dc.typeArtigo em Revista Científica Internacional
dc.contributor.uportoFaculdade de Engenharia
dc.identifier.doi10.1016/j.jece.2014.01.003
dc.identifier.authenticusP-009-4BH
dc.subject.fosCiências da engenharia e tecnologias::Engenharia química
dc.subject.fosEngineering and technology::Chemical engineering
Appears in Collections:FEUP - Artigo em Revista Científica Internacional

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