Please use this identifier to cite or link to this item:
https://hdl.handle.net/10216/106546
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.creator | S. A. Messele | |
dc.creator | O. S. G. P. Soares | |
dc.creator | J. J. M. Orfão | |
dc.creator | C. Bengoa | |
dc.creator | F. Stüeber | |
dc.creator | A. Fortuny | |
dc.creator | A. Fabregat | |
dc.creator | J. Font | |
dc.date.accessioned | 2022-09-07T02:51:49Z | - |
dc.date.available | 2022-09-07T02:51:49Z | - |
dc.date.issued | 2015 | |
dc.identifier.issn | 0920-5861 | |
dc.identifier.other | sigarra:158990 | |
dc.identifier.uri | https://hdl.handle.net/10216/106546 | - |
dc.description.abstract | Activated carbons with different amounts of surface oxygenated groups were used as adsorbents or supports for zero-valent iron (ZVI) catalyst and tested in phenol adsorption and catalytic wet peroxide oxidation, respectively. The results revealed that the surface chemistry of the support plays an important role in phenol adsorption and in the catalytic performance of the respective iron-supported catalysts. ZVI is active when the support has only a limited amount of oxygenated groups on the surface. The presence of acidic oxygenated surface groups is not favorable for the catalytic activity of ZVI in phenol oxidation as well as for phenol adsorption. ZVI supported on activated carbon heat-treated at 900 degrees C yields the best phenol removal, reaching over 85% after 3 h, under the conditions tested: 150 mg L-1 of initial phenol concentration, initial pH set at 3, 30 degrees C, and the stoichiometric amount of hydrogen peroxide for achieving complete mineralization. | |
dc.language.iso | eng | |
dc.relation | info:eu-repo/grantAgreement/FCT - Fundação para a Ciência e a Tecnologia/Projetos Estratégicos/UID/EQU/50020/2013- POCI-01-0145-FEDER-006984/Laboratório de Processos de Separação e Reação - Laboratório de Catálise e Materiais/LSRE-LCM | |
dc.relation | info:eu-repo/grantAgreement/FCT - Fundação para a Ciência e a Tecnologia/Projetos Estratégicos/PEst-C/EQB/LA0020/2013/PROJECTO ESTRATÉGICO - LA 20 - 2013-2014/LA 20 | |
dc.rights | restrictedAccess | |
dc.title | Effect of activated carbon surface chemistry on the activity of ZVI/AC catalysts for Fenton-like oxidation of phenol | |
dc.type | Artigo em Revista Científica Internacional | |
dc.contributor.uporto | Faculdade de Engenharia | |
dc.identifier.doi | 10.1016/j.cattod.2014.03.063 | |
dc.identifier.authenticus | P-009-X7C | |
Appears in Collections: | FEUP - Artigo em Revista Científica Internacional |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
158990.pdf Restricted Access | 457.58 kB | Adobe PDF | Request a copy from the Author(s) |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.