Please use this identifier to cite or link to this item: https://hdl.handle.net/10216/103886
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dc.creatorM. A. Moreira
dc.creatorJ. C. Santos
dc.creatorA. F. P. Ferreira
dc.creatorJ. M. Loureiro
dc.creatorF. Ragon
dc.creatorP. Horcajada
dc.creatorP. G. Yot
dc.creatorA. E. Rodrigues
dc.creatorC. Serre
dc.date.accessioned2022-09-13T09:49:20Z-
dc.date.available2022-09-13T09:49:20Z-
dc.date.issued2012
dc.identifier.issn1387-1811
dc.identifier.othersigarra:61897
dc.identifier.urihttps://hdl.handle.net/10216/103886-
dc.description.abstractThe synthesis of the microporous crystalline titanium(IV) 2-amino-terephthalate (MIL-125(Ti)_NH2; MIL stands for Materials from Institut Lavoisier) was improved at the laboratory scale (40 g) in order to be evaluated as powder for the selective adsorption and separation of xylene isomers and ethylbenzene in liquid phase using n-heptane as eluent. Multi-component breakthrough experiments, conducted at 313 K, have shown a preferential adsorption of ethylbenzene or para-xylene depending on the ethylbenzene concentration. Thus, MIL-125(Ti)_NH2 solid is para-xylene selective in liquid phase in presence of low ethylbenzene concentrations while at higher ethylbenzene concentrations it becomes ethylbenzene selective.
dc.language.isoeng
dc.relationinfo:eu-repo/grantAgreement/FCT - Fundação para a Ciência e a Tecnologia/Programa de Financiamento Plurianual de Unidades de I&D/PEst-C/EQB/LA0020/2011/Projeto Estratégico-LA 20 - 2011-2012/LA 20
dc.rightsrestrictedAccess
dc.subjectEngenharia química
dc.subjectChemical engineering
dc.titleEffect of ethylbenzene in p-xylene selectivity of the porous titanium amino terephtalate MIL-125(Ti)_NH2
dc.typeArtigo em Revista Científica Internacional
dc.contributor.uportoFaculdade de Engenharia
dc.identifier.doi10.1016/j.micromeso.2012.03.039
dc.subject.fosCiências da engenharia e tecnologias::Engenharia química
dc.subject.fosEngineering and technology::Chemical engineering
Appears in Collections:FEUP - Artigo em Revista Científica Internacional

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