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https://hdl.handle.net/10216/103650
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DC Field | Value | Language |
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dc.creator | C. V. Miguel | |
dc.creator | A. Mendes | |
dc.creator | S. Tosti | |
dc.creator | Luís M. Madeira | |
dc.date.accessioned | 2022-09-15T08:31:23Z | - |
dc.date.available | 2022-09-15T08:31:23Z | - |
dc.date.issued | 2012 | |
dc.identifier.issn | 0360-3199 | |
dc.identifier.other | sigarra:64028 | |
dc.identifier.uri | https://hdl.handle.net/10216/103650 | - |
dc.description.abstract | The permeance of a 50 mm thick PdAg (25 wt.% of silver) tubular membrane towards hydrogen was evaluated for hydrogen feed streams or binary mixtures of industrial relevance, namely of H2/CO or H2/CO2. It was proposed a rearrangement of the SievertseLangmuir (SL) equation to account for the inhibition effect on the membrane permeance towards H2 due to the presence of CO or CO2. Such modification is based on the average partial pressure of CO or CO2 and the logarithm-mean driving-force to account for concentration gradients along the axial length of the tubular membrane. Comparison with the original SL equation evidenced relative deviations < 10.7%. The experimental data showed good agreement with the SL model. It was found that carbon monoxide has a much stronger inhibition effect on hydrogen permeation than carbon dioxide. Considering the values obtained for the adsorption enthalpy of each gas, it was concluded that both CO and CO2 adsorb physically on the membrane surface. | |
dc.language.iso | eng | |
dc.relation | info:eu-repo/grantAgreement/FCT - Fundação para a Ciência e a Tecnologia/Projectos de I&DT em Todos os Domínios Científicos/PTDC/EQU-ERQ/098730/2008/Integração de Reactores de Membrana com Processos Adsorptivos usando-se Catalisadores Suportados em Monolitos para a Produção de Hidrogénio de Elevada Pureza/PTDC/EQU-ERQ/098730/2008 | |
dc.rights | restrictedAccess | |
dc.subject | Engenharia química | |
dc.subject | Chemical engineering | |
dc.title | Effect of CO and CO 2 on H 2 permeation through finger-like Pd-Ag membranes | |
dc.type | Artigo em Revista Científica Internacional | |
dc.contributor.uporto | Faculdade de Engenharia | |
dc.identifier.doi | 10.1016/j.ijhydene.2012.05.131 | |
dc.identifier.authenticus | P-002-64K | |
dc.subject.fos | Ciências da engenharia e tecnologias::Engenharia química | |
dc.subject.fos | Engineering and technology::Chemical engineering | |
Appears in Collections: | FEUP - Artigo em Revista Científica Internacional |
Files in This Item:
File | Description | Size | Format | |
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64028.pdf Restricted Access | Artigo original publicado | 1.01 MB | Adobe PDF | Request a copy from the Author(s) |
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