Please use this identifier to cite or link to this item:
https://hdl.handle.net/10216/103029
Author(s): | Hugo Silva Cecilia Mateos-Pedrero Paulo Ribeirinha Marta Boaventura Adélio Mendes |
Title: | Low-temperature methanol steam reforming kinetics over a novel CuZrDyAl catalyst |
Issue Date: | 2015 |
Abstract: | A kinetic study within the low-temperature methanol steam reforming(MSR) reaction was performed over a novel CuZrDyAl catalyst. The physicochemical and catalytic properties of the CuZrDyAl catalyst were compared withthose of a conventional CuO/ZnO/Al2O3 (G66 MR, Sušd-Chemie) sample. The inhouse catalyst displays better performance than the reference G66 MR sample interms of methanol conversion and selectivity. The parameters of a simple powerlaw equation and two mechanistic kinetic models were determined minimizing theresidual sum of squares; the best fitting with the experimental data were obtainedwhen using Model 3, based on the reported work from Peppley et al. (Appl Catal A179:31-49, 1999) for the commercial CuO/ZnO/Al2O3. Noteworthy is the smallnumber of MSR kinetic studies at 170-200 C temperature range. |
Subject: | Engenharia química, Engenharia química Chemical engineering, Chemical engineering |
Scientific areas: | Ciências da engenharia e tecnologias::Engenharia química Engineering and technology::Chemical engineering |
URI: | https://hdl.handle.net/10216/103029 |
Related Information: | info:eu-repo/grantAgreement/FCT - Fundação para a Ciência e Tecnologia/Projetos Estratégicos/UID/EQU/00511/2013 - POCI-01-0145-FEDER-006939/Laboratório de Engenharia de Processos, Ambiente, Biotecnologia e Energia/LEPABE info:eu-repo/grantAgreement/COMISSÃO EUROPEIA/7.º Programa-Quadro de IDT/303476/Integrated low temperature methanol steam reforming and high temperature polymer electrolyte membrane fuel cell/BeingEnergy |
Document Type: | Artigo em Revista Científica Internacional |
Rights: | restrictedAccess |
Appears in Collections: | FEUP - Artigo em Revista Científica Internacional |
Files in This Item:
File | Description | Size | Format | |
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105610.1.pdf | Post-Print version | 1.82 MB | Adobe PDF | ![]() View/Open |
105610.pdf Restricted Access | Artigo original publicado | 518.47 kB | Adobe PDF | Request a copy from the Author(s) |
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