Composite-alumina-carbon molecular sieve membranes prepared from novolac resin and boehmite. Part II: Effect of the carbonization temperature on the gas permeation properties

Abstract

The influence of carbonization temperature on the permeation properties and aging of thin(4 mm) supported carbon molecular sieve membranes (c-CMSM), prepared from in housesynthesized novolac phenolic resin loaded with boehmite nanoparticles, were studied. Justafter membrane carbonization (fresh membrane), high permeance to N2 and O2 and low O2/N2 permselectivities were observed; the highest permeations were observed for carbonization end temperatures between 500 C and 700 C. After leaving the c-CMSM 1 day in theair, a large decrease in the permeation and considerable increase in the permselectivitywere observed due to the reduction of the pore size by oxygen chemisorption and waterphysical adsorption; the permeability to H2 and H2/N2 ideal permselectivity for a membrane carbonized at 550 C are close to palladium membranes for low temperature(<100 C). The effect of the permeation characteristics of the membranes carbonized atvarious temperatures and the removal of water adsorbed in the pores by heat treatmentwere studied.